Abstract

Structural and optical characteristics of manganese doped cadmium sulfide nanoparticles prepared by in situ chemical synthesis using biocompatible Na-alginate biopolymer as a template is reported.

Highlights

  • An important part of modern nanoscience and nanotechnology is the investigation of new materials composed of a polymer matrix lled with semiconductor nanoparticles.[1,2] These types of nanocomposites combine characteristic optical, electrical, magnetic or catalytic properties of semiconductors with the chemical stability and processability of polymers

  • We report on structural and optical characteristics of manganese doped cadmium sul de nanoparticles prepared in aqueous solution by an in situ chemical synthesis using biocompatible Na-alginate biopolymer as a template

  • Fourier transform infrared (FTIR) analyses of the starting biopolymer, Cd2+ crosslinked alginate and cadmium sulfide (CdS)-alginate nanocomposite con rmed the interaction between the nanoparticles and the biopolymer (ESI, Fig. S1†)

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Summary

Introduction

A macromolecule extracted from brown marine algae, is a block-copolymer of (1,4)-linked b-Dmannuronic and a-L-guluronic (G) acids.[15]. We report on structural and optical characteristics of manganese doped cadmium sul de nanoparticles prepared in aqueous solution by an in situ chemical synthesis using biocompatible Na-alginate biopolymer as a template It will be studied how the distorted crystal eld surrounding the Mn2+ ions affects the CdS:Mn-alginate nanocomposites photoluminescence regarding their potential use in bioimaging, since particular photoluminescent characteristics of the nanocomposites coupled with the biocompatibility of alginate open up a possibility of application of the prepared materials as uorescent substrates for tissue imaging in the NIR domain.[38]

Materials
Preparation of the CdS-alginate and CdS:Mn-alginate nanocomposites
Characterization of the CdS-alginate and CdS:Mnalginate nanocomposites
Cell toxicity studies of the CdS-alginate and CdS:Mnalginate nanocomposites
Characterization of the nanocomposites
Optical properties of the nanocomposites
Conclusions
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