Abstract
Solid solubility of Sn in ZnGa2−xSnxO4 Phosphors were investigated by using cathodoluminescence (CL) and X-ray diffraction (XRD) measurements. The CL spectra showed that the dramatic transition behavior of the CL emission energy peak at the Sn mole fraction of 0.0004 in the ZnGa2−xSnO4 was observed. The XRD curves showed that the second phase corresponding to the ZnSnO3 together with an original phase related to the ZnGa2O4 was observed at the Sn mole fraction of 0.0004 in ZnGa2−xSnxO4. These results indicate that the Sn mole fraction limit for the single phase formation in ZnGa2−xSnxO4 Phosphors is 0.0002.
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