Abstract

Two qualitatively different SmA structures exhibiting herringbone-type layer patterns, to which we refer as the Defectless Smectic Herringbone (DSH) and the Dislocation Decorated Smectic Herringbone (DDSH) pattern are studied by a Landau-de Gennes-Ginzburg mesoscopic approach. Liquid crystal structures are described in terms of a nematic director field and a smectic complex order parameter. It is demonstrated that, in the proximity of the N-SmA phase transition, a melting of smectic layers could be realised even for relatively weakly-tilted smectic layers in DSH patterns (i.e. θt ≈ 100) for type I Sm4 phase. The width of melted region could be relatively large with respect to bulk values of the smectic characteristic lengths. In addition, a critical value of θt is determined at which a DDSH pattern is expected to appear.

Highlights

  • Recent years have brought increasing interest in soft nanocomposites [1]

  • This smectic pattern dislocations the smectic periodicity at x=0 is given by roughly mimics the experimentally obtained herringbone-type patterns studied in [14]. In such liquid crystalline (LC) configurations two qualitatively different equilibrium patterns could be formed, to which we refer as the Defectless Smectic Herringbone (DSH) pattern and the Dislocation Decorated Smectic

  • We demonstrate the changes in η ( x ) and θ ( x ) behavior on increasing temperature towards the N-smectic A (SmA) phase transition for θ t = 100 and κ = 0.1, where the initial configuration obtained for λ / d 0 = 1 is shown in figure 3b

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Summary

Introduction

Recent years have brought increasing interest in soft nanocomposites [1]. Typically, such systems consist of a soft matrix containing nanoparticles, where each component contributes a specific desired system’s property. Where the positive quantities K1, K2 and K3 are the splay, twist and bend Frank nematic elastic constants, respectively This contribution enforces a homogeneous alignment of n along a symmetry breaking direction. Α 0 and β are positive material constants and we consider the case of 2nd order bulk nematic-SmA phase transition at T=Tc. Below Tc the condensation term imposes the bulk equilibrium value of the translational order parameter α 0 ( Tc − T ). SmA phase [15], corresponding roughly to materials characterized by κ < 1 / 2 and κ > 1 / 2 , respectively In the latter case dislocations are relatively more introduced into SmA patterns if a smectic layer frustration is enforced

Parameterisation and Euler-Lagrange equations
Defectless Smectic Herringbone pattern
Dislocation Decorated Smectic Herringbone patterns
Conclusions
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