Abstract

Herein, a user-friendly and portable smartphone-integrated printed-paper sensor was designed with Cu@Ag nanoparticles (NPs) for on-site monitoring of dimethoate pesticide in food samples, and the results obtained are compared with those obtained by UV–vis spectrophotometry. The working principle for identification of dimethoate pesticide is the change of yellow color NPs to reddish-yellow with associated bathochromic shift of absorption peak when pesticide introduced onto the fabricated paper or glass vial containing the NPs. A smartphone-color detector App and colorimetry were used for quantitative analysis of dimethoate in food samples. Linearity range for analysis of dimethoate using paper sensor and colorimetry were 100–2000 µgL−1 and 50–2500 µgL−1 with detection limit of 30 and 16 µgL−1, respectively. The advantages of using smartphone-integrated paper devices are rapid, instrument-free detection and economic in terms of consumption of lower amounts of NPs solution compared to other NPs-based colorimetric methods.

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