Abstract

On the basis of the idea that the injecting energy will improve the conditions for the formation of Cooper pairs, a smart meta-superconductor (SMSC) was prepared by doping luminescent nanocomposite Y2O3:Eu3+/Ag in MgB2. To improve the superconducting transition temperature (TC) of the MgB2-based superconductor, two types of Y2O3:Eu3+/Ag, which has the strong luminescence characteristic, with different sizes were prepared and marked as m-Y2O3:Eu3+/Ag and n-Y2O3:Eu3+/Ag. MgB2 SMSC was prepared through an ex situ process. Results show that when the dopant content was fixed at 2.0 wt.%, the TC of MgB2 SMSC increased initially then decreased with the increase in the Ag content in the dopant. When the Ag content is 5%, the TC of MgB2 SMSC was 37.2–38.0 K, which was similar to that of pure MgB2. Meanwhile, the TC of MgB2 SMSC doped with n-Y2O3:Eu3+/Ag increased initially then decreased basically with the increase in the content of n-Y2O3:Eu3+/Ag, in which the Ag content is fixed at 5%. The TC of MgB2 SMSC doped with 0.5 wt.% n-Y2O3:Eu3+/Ag was 37.6–38.4 K, which was 0.4 K higher than that of pure MgB2. It is thought that the doping luminescent nanocomposite into the superconductor is a new means to improve the TC of SMSC.

Highlights

  • Improving the superconducting critical transition temperature of materials is an important scientific and technical problem in condensed matter physics and materials science

  • The results indicate that the EL intensity of the luminescent micro Y2O3:Eu3+/Ag (m-Y2O3):Eu3+/Ag nanocomposite and nano Y2O3:Eu3+/Ag flakes (n-Y2O3):Eu3+/Ag is remarkably improved primarily due to the composite luminescence of the electroluminescence of Eu3+ centric and the surface plasma-enhanced photoluminescence of Ag

  • MgB2 of smart meta-superconductor (SMSC) was prepared through an ex situ process to improve the TC of the MgB2-based superconductor on the basis of the idea that the injecting energy will improve the conditions for the formation of Cooper pairs

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Summary

Results and Discussion

The impurity effect of the dopant dominated when the doping concentration increased to a high range, which led to a low TC These results indicate that doping luminescent nanocomposite materials effectively adjusts and improves TC at an appropriate doping concentration. A new kind of commercial MgB2 with a small ΔT of 0.8 K was used, and we obtained a similar conclusion, which further proves the effectiveness of this method

Conclusions
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