Small-Amplitude and Mixed-Mode pH Oscillations in the Bromate−Sulfite−Ferrocyanide−Aluminum(III) System

Klara Kovacs,Vladimir K Vanag,Marcin Leda,Irving R Epstein

doi:10.1021/jp807840g

Small-Amplitude and Mixed-Mode pH Oscillations in the Bromate−Sulfite−Ferrocyanide−Aluminum(III) System

Klara Kovacs, Vladimir K Vanag + Show 2 more

https://doi.org/10.1021/jp807840g

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Journal: The Journal of Physical Chemistry A	Publication Date: Dec 16, 2008
Citations: 21

Affiliation: Brandeis University

#Stirred Flow Reactor #Precipitation Equilibrium + Show 8 more

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Abstract

The BrO(3)(-)-SO(3)(2-)-Fe(CN)(6)(4-) (BSF) pH-oscillatory system is coupled to the Al(OH)(3) precipitation equilibrium (BSFA system) and studied in a stirred flow reactor. The dynamic behavior of the BSFA system differs significantly from that of the BSF system. In addition to the large-amplitude pH oscillations found in the BSF system, new small-amplitude and mixed-mode oscillations occur. A detailed mechanism of the BSFA system is developed and investigated.

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