Sluggish kinetics in the parking lot model

Abstract

We investigate, both analytically and by computer simulation, the kinetics of a microscopic model of hard rods adsorbing on a linear substrate. For a small, but finite desorption rate, the system reaches the equilibrium state very slowly, and the long-time kinetics display three successive regimes: an algebraic one where the density varies as , a logarithmic one where the density varies as , followed by a terminal exponential approach. A mean-field approach fails to predict the relaxation rate associated with the latter. We show that the correct answer can only be provided by using a systematic description based on a gap-distribution approach.