Abstract

Two mixed-valence Co(ii)/Co(iii) complexes of [CoII(phen)3][CoIII(HATD)2]2·3DMA·3.5H2O (1) with field induced single-molecule magnet behavior, and [CoII(terpy)2][CoIII(HATD)2]2·4DMA·H2O (2) with a gradual thermal spin crossover (SCO).

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