SLES/CMEA mixed surfactant system: Effect of electrolyte on interfacial behavior and microstructures in aqueous media

Abstract

In aqueous anionic sodium lauryl ether sulfate (SLES) solution, presence of nonionic cocamide monoethanolamine (CMEA) depicts intriguing interfacial and bulk properties. CMEA has poor water solubility but can be readily solubilized in SLES solution to form mixed micellar aggregates as revealed by surface tension measurements. Sphere-to-rod micellar transition in aqueous SLES-CMEA binary mixtures occurs at higher surfactant concentration (total surfactant concentration beyond 15 wt%), inducing a sharp growth in the viscosity (>1000 cP). Nevertheless, adding NaCl in SLES-CMEA mixtures, substantial growth in viscosity is perceived at much lower surfactant concentration (~5–10 wt%) attributed to the formation of intertwined worm-like micelles. Micellar sizes were obtained by dynamic light scattering (DLS) measurements and small-angle neutron scattering (SANS) investigations is used to determine micellar shapes and aggregation number for SLES-CMEA mixtures. Furthermore, it is observed that foaming behavior of SLES can be modulated by CMEA ascribed to the change in foam film rigidity. Corresponding experiments were also performed with nonethoxylated counterpart sodium lauryl sulfate (SLS) under analogous condition for comparison. The study reported here may prove to be an appropriate tactic to alter not only the rheology or foaming behavior of SLES-CMEA mixed surfactant system but also provide pre-solubilized composition of CMEA which could be highly beneficial for personal care products enabling CMEA blending at room temperature, which otherwise needs high temperature mixing.