Abstract

Abstract The functionalized tricyclo[6.3.0.01,5]- and [5.3.1.01,5]-undecanes are newly synthesized from endo- and exo-tricyclo-[6.3.0.01,6]undecan-5-ols by skeletal rearrangements using the solvolyses of their tosylates. Furthermore, a novel biologically active compound is derived readily from the rearrangement products.

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