Size-resolved carbonaceous aerosols at near surface level and the hilltop in a typical valley city, China

Abstract

The lack of light–absorbing aerosols vertical distributions data largely limited to revealing the formation mechanism of severe haze pollution in Chinese cities. Based on the synchronous measurements of size–resolved carbonaceous aerosols and meteorological data at near surface level and hilltop (about 620 m above the valley) in Lanzhou of northwest China, this study compared organic and elemental carbon (OC, EC) size distributions at the two altitudes and revealed the key influencing factors in a typical urban valley, China. The winter OC size distributions were typically bimodal with two comparable peaks in the accumulation and coarse modes, while those in summer were unimodal with the highest value in the size bin of 4.7–5.8 μm. The size-resolved OC and EC at near the surface were significantly higher than those at the hilltop. The difference (concentrations and size distributions) of OC and EC between the surface and hilltop in summer was much smaller than that in winter due to stronger vertical mixing and larger summer SOC contributions at the hilltop. The winds paralleling with running urban valley were conducive to dispersing the air pollutants from near the surface to the upper air. The roles of horizontal and vertical dispersions to carbonaceous aerosols were comparable at near the surface, while horizontal dispersion was more important at the hilltop. Furthermore, the vertical dispersion was a main factor controlling size–resolved carbonaceous aerosols under highly polluted conditions in a typical urban valley. This study will provide the basis for regulation of severe haze pollution over complex terrain.