Size-matched hierarchical porous carbon materials anchoring single-atom Fe-N4 sites for PMS activation: An in-depth study of key active species and catalytic mechanisms

Abstract

Single-atom catalysts are considered to be one of the most promising catalysts for AOPs. However, how to design and synthesize cost-effective and highly loaded single-atom catalysts is the bottleneck limiting its development and application. In this study, we report a highly loaded single-atom iron catalyst (Fe-SAC-BC) using waste biomass as a carbon carrier to anchor Fe-N4 sites. The catalyst showed excellent catalytic performance and stability in wastewater treatment. Unlike conventional radical oxidation, the non-radical degradation process of Fe-N4 as the active site and high-valent iron-oxygen intermediates as the key active species identified by burst and probe experiments. DFT calculations and molecular dynamics simulations were applied to the catalytic mechanism of Fe-SAC-BC, in which Fe (III)-N4 is the most likely active site and Fe (IV)-OH is the most dominant active species. This study provides new strategies and understanding for the design of novel single-atom catalysts and the mechanistic probing of the non-radical pathways of AOPs.