Abstract

Our previous studies indicate that small additions of nano-scaleRE2BaCuO5 (RE211, RE: rare elements) form nano-sized compositional fluctuations during themelt-growth process and thus act as field induced pinning centres. The solubility,peritectic temperature, and atomic size of these nmRE211 additives alter theJc–H performance. To further reveal the effect of size and amount of RE211 additives, in this study,Y2Ba1Cu1O5 (Y211) particles of two different sizes, micro-scale(µm) and nano-scale (nm), were used. The superconducting results indicate that the contribution ofJc in high field regions is larger in nmY211 thanµmY 211. The microstructureresults imply that µmY 211 particles tend to form Y-rich regions in the core shell, while nmY211 particles tend toproduce regions with Y fluctuations and high defect density. These different results areattributed to the reactions between the Y211 additions and the 123 matrix during themelt-textured growth process.

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