Abstract

Er3+/Yb3+ co-doped LiYF4 nanocrystals were prepared by a facile solvothermal method. By adjusting the LiOH concentration, LiYF4 crystals with the size range from 16 nm to 2.0 μm were synthesized. Under the excitation by a 976 nm laser, upconversion quantum efficiency of the LiYF4: Er3+/Yb3+ samples were measured. It was observed that upconversion quantum efficiency tended to decrease with the reduction of particle size from microscale to nanoscale. A model was proposed to clarify the surface quenching mechanism influencing the size-dependent upconversion luminescence.

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