Abstract

It is well known that some ferromagnetic properties like Curie temperature are size dependent. In this Letter we will report that the spin-reorientation temperature of Nd 2Fe 14B material is also size dependent. By using a surfactant-assisted ball milling technique, Nd 2Fe 14B nanoparticles with different size about 6, 20 and 300 nm were successfully obtained. Spin-reorientation transition temperature of the NdFeB nanoparticles was then determined by measuring the temperature dependence of DC and AC magnetic susceptibility. It was revealed that the spin-reorientation transition temperature ( T s r ) of the nanoparticles is strongly size dependent. T s r of the 300 nm particles is lower than that of the bulk raw material while the T s r of the 20 nm particles is significantly lower than that for the 300 nm particles. The physics behind this size dependence is discussed.

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