Size dependent electrical and magnetic properties of ZnFe2O4 nanoparticles synthesized by the combustion method: Comparison between aspartic acid and glycine as fuels

Abstract

Using two different fuels such as aspartic acid and glycine, the spinel zinc ferrite nanoparticles were synthesized by the combustion method at different pH values. The thermochemical calculations for both the fuel assisted materials and its adiabatic flame temperature were calculated. The X-ray diffraction (XRD) pattern revealed the formation of single phase ZnFe2O4 with high crystallinity. The characteristic functional groups of Fe3O and Zn3O were identified through FTIR analysis. Uniform size distribution of spherical particle in the average size range of 35–100nm was inferred from SEM images. The room temperature DC conductivities of ZnFe2O4 particles prepared by using aspartic and glycine are in the order of 10−7 and 10−8 respectively. The dielectric spectral analysis inferred that the obtained dielectric constant is high at low frequency and decreases with increase in frequency. This dielectric behavior is in accordance with the Maxwell–Wagner interfacial polarization. VSM and Mössbauer analysis revealed that the prepared material exhibits paramagnetic behavior and Fe3+ state of iron content in ZnFe2O4 at room temperature.