Abstract
Size-controlled crystalline basic nanoporous coordination polymers of IRMOF-3 (Zn4O(H2N-TA)3) and its catalytically study for synthesis of tetrahydro-chromenes was investigated. IRMOF-3 was found to be an efficient, selective and waste-free green solid base for the coupling reaction of dimedone, aldehydes, and malononitrile. The catalyst can be isolated from the reaction mixture and reused at least 5 times.
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