Abstract
In this study we present for the first time site (N1-H / N3-H) and bond (N-H / C-H) selectivity of H− formation in 1-methylthymine, 3-methyluracil and deuterated thymine (C positions) triggered by potassium molecule collisions. By comparing the H loss of these molecules with H loss in thymine and uracil and setting the energy one can predict site and bond selectivity in these set of molecules.
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