Abstract

An attempt has been made to analyse the sintering data of urania powder compacts prepared form its precursor ammonium diuranate calcined and sintered in hydrogen atmosphere for various soaking times and temperatures. Better sintering behaviour was observed in compacts prepared from powders calcined below 800 ° C, which were non-crystalline under X-ray diffraction study. Frenkel's sintering mechanism as applicable for the non-crystalline powders was applied to understand the densification behaviour in which the viscosity term was linearly related to shear stress and strain rate as also its relationship with time was assumed to be either linear or exponential in nature. A plot between shear stress (to induce densification) and time indicated that (i) a critical time ( T crit ) is necessary to induce any observable sintering stress in these powders and T crit , values increased with decrease in calcination temperature and (ii) the amount of shear stress increased with higher sintering temperatures and was related to time, exponentially.

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