Sintering process of inkjet-printed silver patterns using a heated inert gas

Abstract

In this study, we introduce a thermal sintering process using a heated inert gas as a new sintering method. The heated gas flow is formed by passing nitrogen (N2) gas through a heating head of 300 to 700°C, and the desired substrates are then exposed to the heated gas flow through a 400mm long and 5mm wide slit-nozzle. Sintering performance of Ag films was characterized by analyzing the electrical resistivity and metallographic structures according to the temperature change of the heating head. The temperature distribution of the heating region is analyzed by infrared (IR) thermal imaging and surface temperature measured by thermo-label tape. To test the feasibility of the proposed method for application to printed circuit board (PCB) manufacturing, we performed a reliability evaluation using the printed Ag patterns under the standard of the Institute for Interconnecting and Packaging Electronic Circuit (IPC), TM650. Various reliability test patterns were created by Ag inkjet-printing on both a rigid flame retardant 4 (FR4) substrate and a flexible polyimide (PI) film substrate. The reliability evaluation includes withstanding voltage, adhesive strength, thermal shock, pressure cooker, and bending tests. The surface wettability of the substrates was controlled to obtain high quality fine and uniform patterns by UV/O3 treatment after coating a fluoropolymer thin film.