Abstract

The sintering of alumina doped with magnesia‐based additives to translucency previously has been possible only in atmospheres of hydrogen or oxygen or under vacuum. This paper reports on the sintering of alumina in N2–H2 atmospheres that contain as little as 2% H2, where optical transparency that is equivalent to that of normal H2 sintering is achieved. In an effort to explain these results, experiments that vary the content of H2 and H2O, as well as the changes in the dynamic atmosphere, have been conducted. The evidence indicates that the final‐stage sintering involves a point‐defect pair mechanism that includes hydrogen interstitials and nitrogen solutes.

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