Abstract

Sintering injection-moulded WC–7 wt% Ni in a hydrogen atmosphere at temperatures higher than 900°C resulted in an inhomogeneous microstructure, as Ni2W4C (η phase) preferentially developed near the surface of specimens. Subsequent to sintering at temperatures higher than the liquid-phase formation temperature, the surface of specimens was virtually composed of η phase. This arose from the excessive decarburization occurring near the surface of specimens, and the exudation of the Ni-based metal binder towards the surface of specimens. Primarily caused by the dissolution of W into the Ni binder phase, the saturation magnetization of WC–7 wt% Ni decreased at temperatures lower than 1000°C.

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