Sintering, mechanical properties and hydrothermal resistance of ZrO2/ZrSiO4 slip cast composites

Abstract

Yttria-doped tetragonal zirconia polycrystalline (Y-TZP) is one of the most widely used materials in thermal applications and as a structural component due to its mechanical properties. Its drawbacks are the high cost of the starting raw materials and its polymorphic transformation to monoclinic phase associated with the occurrence of mechanical failures. In the present work, tetragonal zirconia materials were obtained by slip casting and also ZrO2/ZrSiO4 composites by partially replacing the zirconia with low cost and high corrosion resistance zircon. The different parts showed a high microstructural homogeneity, as well as high hardness and Young's modulus (up to 16.7 and 354 GPa, respectively), even with the incorporation of 20 vol% zircon. The zircon-containing composites subjected to hydrothermal low-temperature degradation (LTD) at 205 °C for 240 h exhibited similar mechanical properties, unaffected microstructural integrity, and a crystallographic phase composition equal to the as-sintered samples, without phase transformation from t-ZrO2 to m-ZrO2.