Abstract

The novel cyclophane diradical 1 possesses a singlet ground state with a singlet–triplet energy gap (ΔEST) of −0.20 and −0.24 kcal mol−1, as measured with SQUID magnetometry and EPR spectroscopy, respectively. This large ΔEST may in part be associated with the two parallel 3,3′-biphenyl exchange coupling pathways (ECPs).

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call