Abstract
The photochemical behavior of tricyclo [5. 2. 2. 02, 6] undeca-3, 10-dien-9-one ring system (4), which was prepared by Diels-Alder reaction of cyclohexadienone derivatives and cyclopentadiene, has been studied under triplet sensitization and direct irradiation. In the triplet state, this ring system undergoes the oxa-di-π-methane (ODPM) rearrangement, while the 1, 3-acyl migration occurs from the singlet state. The triplet energy was estimated to be between 70 and 72 kcal/mol on the basis of sensitization by various sensitizers.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
