Abstract
Silylium ions undergo a single-electron reduction with phosphanes, leading to transient silyl radicals and the corresponding stable phosphoniumyl radical cations. As supported by DFT calculations, phosphanes with electron-rich 2,6-disubstituted aryl groups are sufficiently strong reductants to facilitate this single-electron transfer (SET). Frustration as found in kinetically stabilized triarylsilylium ion/phosphane Lewis pairs is not essential, and silylphosphonium ions, which are generated by conventional Lewis adduct formation of solvent-stabilized trialkylsilylium ions and phosphanes, engage in the same radical mechanism. The trityl cation, a Lewis acid with a higher electron affinity, even oxidizes trialkylphosphanes, such as tBu3 P, which does not react with either B(C6 F5 )3 or silylium ions.
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