Single Ru atoms dispersed on MoSe2/MXene nanosheets with multiple interfaces for enhanced acidic hydrogen evolution

Abstract

Exposing more catalytic active sites is an effective strategy to enhance the catalyst activity for hydrogen evolution reaction (HER). Herein, Ti3C2Tx MXene served as a substrate to load thin and curved 2H–MoSe2 nanosheets by a typical hydrothermal method, forming MoSe2/MXene heterointerface with the fully exposed Mo edge sites. And then, atomically dispersed Ru single atoms (RuSAs) were successfully anchored on the MoSe2/MXene (RuSAs@MoSe2-MXene). The X-ray absorption near edge structure (XANES) demonstrates that Ru is loaded as single atoms on MoSe2 and MXene. The prepared sample exhibits improved catalytic activity with a small overpotential of 49 mV at 10 mA cm−2 and a low Tafel slope of 52 mV dec−1 for HER in 0.5 M H2SO4. It also exhibits excellent stability with a small attenuation voltage of 10 mV for 120 h at 10 mA cm−2 in 0.5 M H2SO4. When assembled into a two-electrode system of RuSAs@MoSe2-MXene||RuO2, it only requires a relatively low potential of 1.626 V at 10 mA cm−2 to drive overall water splitting (OWS). Control experiments disclose the highly improved performance can be primarily attributed to the introduced RuSAs and MoSe2/MXene heterointerfaces exposing more active sites of Ru and Mo. Moreover, the high conductivity of MXene can increase charge transfer in HER process. The interface engineering with multiple interfaces can provide fresh impetus for the development of efficient HER catalysts.