Abstract

Single-crystalline trumpetlike Zn3P2 nanostructures composed of hollow cones supported by nanowires have been prepared via a simple thermochemical method, which utilized ZnS and GaP as the source materials. The as-synthesized nanostructures are composed of single-crystalline Zn3P2 nanowires with diameters of ∼50nm and large diameter hollow cones with diameters increasing from 50nm at the bottom to 600nm at the top. Photoluminescence study of the trumpetlike Zn3P2 nanostructures shows a broad emission centered at ∼585nm at room temperature.

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