Single crystal studies of electric field gradients in dilute alloys. II. Copper based crystals

Abstract

For Pt. I see abstr. A1732 of 1972. The electric field gradients at nearest and in some cases next nearest host Cu nuclei to various impurities in dilute Cu alloy single crystals have been determined by the quadrupole effects in nuclear magnetic resonance. The impurities are In, Sn, Sb and Ge. The field gradients at nearest neighbour sites are far from rotational symmetric around the direction towards the impurity and in the case of CuGe it does not even have the main component in that direction. These results question the validity of the theoretical models assuming spherical symmetry for the charge density around the impurity, at least in host metals like copper.