Abstract
Electron paramagnetic resonance (EPR) studies have been carried out on Cu(II) doped Cd(C 5H 5NO) 6(BF 4) 2 in single crystal and powder forms at 300 K. Angular variation of hyperfine structure lines shows the presence of two magnetic sites, indicating possible twinning in the Cd lattice. From the mean values of two sites, the angular variation plot is fitted to an orthorhombic spin Hamiltonian. The observed orthorhombic g values and the very low A 11 value (| A 11|=107.8×10 −4 cm −1) are unusual for a hexakis coordinated system. This unique behavior is explicable in terms of the static Jahn–Teller (JT) effect.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
