Abstract
The anisotropic proton conductivity of a large-sized single crystal of the supramolecular, commensurate host–guest inclusion compound constituted by a polyanionic thiourea–chloride matrix defining channels in which the diquinuclidinium cations [Q2H]+ are hosted is reported. Specimens in the millimetre scale display an anisotropy factor of about 100, with electrical conductivities along molecular channels of the order of 10-4 S cm-1 at room temperature.
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