Single-Chain Inherent Elasticity of Macromolecules: From Concept to Applications.

Abstract

"The Tao begets the One. One begets all things of the world." These words of wisdom from Tao Te Ching are of great inspiration to scientists in polymer materials science and engineering: The "One" means an individual polymer chain while polymer materials consist of numerous chains. The understanding of the single-chain mechanics of polymers is crucial for the bottom-up rational design of polymer materials. With a backbone and side chains, a polymer chain is more complex than a small molecule. Moreover, an individual polymer chain is usually placed in a complicated environment (such as solvent, cosolute, and solid surface), which significantly affects the behaviors of the chain. With all these factors, it is hard to fully understand the elastic behaviors of polymers. Herein, we will first introduce the concept of the single-chain inherent elasticity of polymers, which is a fundamental property determined by the polymer backbone. Then, the applications of inherent elasticity in quantifying the effects of side chains and surrounding environment will be summarized. Finally, the challenges in related fields at present and potential research directions in the future will be discussed.