Single bubble growth during water electrolysis under microgravity

Abstract

Single bubble evolution on a micro-electrode (Pt, φ = 0.2 mm) was observed in 0.36 M KOH solution under terrestrial (1-G) and microgravity (μ-G) environments. The bubble size during galvanostatic electrolysis ( j = −2.6 × 10 3 A m −2) was measured by CCD images, which allowed us to calculate the gas evolution efficiency, f G, by comparison with the consumed charge. The efficiency under μ-G increased until 1 s after starting electrolysis and then reached constant value ( f G = 0.85), while, under 1-G, it showed a lower value and remarkably decreased 2 s after the beginning of the measurement. Such differences between μ-G and 1-G were explained by the mass transfer rate of the dissolved gas. Bubble-induced microconvection dominated the mass transfer under μ-G without any buoyancy force, on the other hand, the single-phase free convection (microscopic natural convection) influenced the bubble growth under 1-G.