Abstract
The synthesis of cationic binuclear palladium complexes of the type {(μ-X)[Pd(C 6F 5)L 2][Pd(C 6F 5)L′]}ClO 4 (L = N or P donors) is described. X can be a pseudohalide, such as CN, SCN or N 3, or a halide when L 2 is a bidentate N-ligand, such as bipy. Trinuclear complexes of the type {[(PPh 3) 2Pd](μ-X) 2[Pd(C 6F 5)L 2] 2}ClO 4 have only been obtained for X = CN. For X = other pseudohalide or halide, rearrangement reactions render binuclear double-bridged species along with binuclear single-bridged species of the above-mentioned type. The preparation of a pentanuclear complex {[Pd(μ-CN) 4][Pd(C 6F 5)(PPh 3) 2] 4}(ClO 4) 2 is also described.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
