Abstract
Single-atom solutions are proposed to promote CO2 capture for carbon neutralization. Copper, iron, manganese and boron based single-atom DMF solution along with iron and manganese based single-atom ethanol solution are developed scientifically. The DFT simulation and experiment are performed to analyze the system of single-atom solution and CO2. It is shown that copper, iron and boron single atoms promote the solution to absorb carbon dioxide. Manganese single atom shows little intensification effect for carbon dioxide absorption. More importantly, copper single atom also promotes CO2 desorption at low temperatures. Based on the interaction energy and desorption energy barrier, it is concluded that copper and boron based single-atom solutions show outstanding CO2 capture performance. Their CO2 desorption energy were assessed as 1.65 GJ/t CO2 and 0.97 GJ/t CO2, which are 56.58% and 74.47% lower than the conventional amine system.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
