Simultaneously realized large low-temperature magnetocaloric effect and good mechanical properties in Ni36Co13Mn35Ti16 alloy

Abstract

In this work, we present the observation of large low-temperature magnetocaloric effect and good mechanical properties in the Ni36Co13Mn35Ti16 alloy. The phase transition behaviors, magnetocaloric effect, and mechanical properties for the Ni36Co13Mn35Ti16 non-textured polycrystalline alloy were systematically investigated. Under the magnetic field changes of 5 T, a typical meta-magnetic behavior with a large magnetization change of about 110 A m2 kg−1 between the austenite and martensite can be observed, the maximum magnetic entropy changes (ΔSm) of the Ni36Co13Mn35Ti16 alloy is ∼16.1 J kg−1 K−1 at 148 K. Furthermore, the maximum compressive stress and strain are 894 MPa and 8.0%, respectively. The scanning electron microscope and first-principles calculations were used to analyze the fracture mechanism and the bonding interaction. In the combination of the large low-temperature magnetocaloric effect and good mechanical properties, the Ni36Co13Mn35Ti16 alloy has a good prospect for low-temperature magnetic refrigeration applications.