Simultaneous voltammetric determination of dopamine and ascorbic acid at an electrode modified with the gold-palladium binary system

Abstract

The catalytic activities of gold, palladium, and rhodium particles and their binary systems electrodeposited on the surface of a glassy-carbon electrode in the oxidation of dopamine and ascorbic acid are compared. As compared to individual noble metals, the Au-Pd binary system exhibits a higher catalytic activity that manifests itself in a multiple increase in the oxidation current of the mediator and in a decrease in the oxidation potential of the substrate. It is found that dopamine and ascorbic acid can be simultaneously determined by voltammetry at an electrode modified with the Au-Pd binary system. The catalytic currents of substrate oxidation are linear functions of the concentrations in the ranges from (1 × 10−3 to 1 × 10−7) M for dopamine and from (5 × 10−3 to 1 × 10−6) M for ascorbic acid.