Abstract

The present study attempts to generate chlorine dioxide (ClO 2) gas continuously by chlorate–chloride process and to utilize it further to clean up SO 2 and NO x gases simultaneously from the flue gas in the lab-scale bubbling reactor. Experiments were carried out to examine the effect of various operating parameters like input SO 2 concentration, input NO concentration, pH of the reaction medium, and ClO 2 feeding rate on the SO 2 and NO x removal efficiencies at 45 °C. Complete oxidation of NO into NO 2 occurred on passing sufficient ClO 2 gas into the scrubbing solution. SO 2 removal efficiency of about 100% and NO x removal efficiency of 66–72% were achieved under optimized conditions. NO x removal efficiency decreased slightly with increasing pH and NO concentration. Input SO 2 concentration had marginal catalytic effect on NO 2 absorption. No improvement in the NO x removal efficiency was observed on passing excess of chlorine dioxide in the scrubbing solution.

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