Simultaneous removal of arsenite and arsenate from mining wastewater using ZIF-8 embedded with iron nanoparticles

Abstract

Arsenic contamination is an increasing global environmental problem, especially in mining industry wastewater where both arsenite (As(III)) and arsenate (As(V)) have been routinely detected. In this paper, a novel porous metal-organic framework material (ZIF-8) was composited with iron nanoparticles (FeNPs) to form a functional material (ZIF-8@FeNPs) for the simultaneous removal of As(III)/(V) from wastewater. The material effectively removed both As(III) and As(V) with removal efficiencies of 99.9 and 71.2%, respectively. Advanced characterization techniques including X-ray photoelectron spectroscopy (XPS) and Fourier infrared (FTIR) indicated that removal of As(III) and As(V) involved complex formation. Adsorption kinetics followed a pseudo-second order kinetics indicating adsorption involved chemisorption. After four cycles of reuse the he removal rate of As species was still relatively high at > 60% When ZIF-8@FeNPs were used to remove As from real wastewater from acid mines the removal efficiency was 94.27%. Finally, a As(III) and As(V) removal mechanism was proposed.