Simultaneous realization of two approaches to white light in single-component phosphors.

Abstract

A novel single-component warm white light-emitting Sr(2)Ca(0.995)MoO(6): Sm(3+) (0.005) phosphor was synthesized by solid-state reaction. The photoluminescence excitation spectra ranging from 300 to 450 nm and 460 to 500 nm broadly are observed. Direct full-color warm white light [(x, y) = 0.3221, 0.3525] was realized in this single-phase phosphor with exposure to 380 nm UV light. When this phosphor is pumped by 466 nm radiation we obtained yellow emission with an intense red component, suggesting that this material is also competitive as a blue-pumped yellow phosphor. Thus two approaches to white light are realized simultaneously in Sm(3+) doped single-component phosphor for the first time. The quantum yield and the reliability of the as-synthesized phosphors for White LED applications were also investigated.