Simultaneous Occurrence of Miscible and Immiscible Displacement Processes During Solvent Displacement of Heavy Oil: A Parametric Analysis Using Visual Capillary-Tube Experiments

Abstract

Summary Oil/solvent mixing is essential during solvent-injection applications to reduce the viscosity of oil, but mass transfer by diffusion becomes slower because the oil becomes heavier. Thus, an interface exists between the oil and solvent at certain times, being stronger in the beginning of the process. This results in an immiscible displacement controlled by the capillary forces while mixing is in progress. It is of practical and fundamental importance to determine the mechanisms responsible for the displacement of heavy oil and the behavior of solvents (acting as both immiscible and miscible displacement agents) because it could be advantageous to accelerate the dilution of heavy oil in many circumstances, including heterogeneous (fractured, layered, wormholed) systems. This is a complex process consisting of multiple pore phases (oil, solvent, their mixtures, and aqueous and vapor phases) at the same time, while different mechanisms such as capillary imbibition, miscible interaction (diffusion and convection), and gravity also act simultaneously. To investigate this complex phenomenon for different oil/solvent systems, a novel experimental method was used. The underlying mechanisms that dominate the solvent displacement process were comprehensively identified. The movement and evolution of interfaces among different fluid phases in glass capillary tubes were observed and recorded. Oil samples with different viscosities were used to examine the effects of oil viscosity on the mass transfer accelerated by imbibition transfer. The effects of temperature, wettability, and boundary conditions on the interaction of miscible fluid pairs were also studied. Pentane, heptane, and decane were used as the solvent phases. Advanced photographic techniques using ultraviolet (UV) light and dyed fluids were applied to better track the flow of different phases in the mixing zone. The experiments demonstrated a slowly smearing interface between the solvent and viscous oil. A unique natural convection was induced, with the combined effect of gravity, diffusion (mixing), and capillarity all contributing to the recovery of heavy oil. On the basis of the saturation method, boundary condition, and the Bond number, four different motion modes of mixing zone and interfaces of miscible fluids in the capillary tube were revealed and categorized to identify the degree of interface development (immiscible flooding). Also, the mixing zone, mass flux, and flow behavior were quantified using dimensionless parameters. The results indicate that priority may be given to a solvent with a high interfacial tension (IFT) for the solvent-based oil-recovery technique because of a strong imbibition and further enhancement of the dilution and displacement processes under conditions of a similar viscosity ratio. The data provided will be useful for the accuracy of modeling studies, especially for complex geologies where oil/solvent interaction is critically difficult to develop in order for mixing to occur.