Simultaneous measurements of total gaseous mercury at four sites on a 800 km transect: spatial distribution and short-time variability of total gaseous mercury over central Europe

Abstract

Over a distance of approximately 800 km simultaneous measurements of total gaseous mercury (TGM) were performed at four sampling sites between Stockholm and Berlin. The time resolution of mercury concentration measurements was 5 min. During the sampling period from 26 June to 7 July 1995, event sampling for precipitation was carried out using bulk samplers. In addition to the mercury data, the most common meteorological and air-quality parameters were determined. Comparing the TGM background concentrations at the four sites, a weak but statistically significant south-to-north declining TGM gradient was found. From the most southern sampling site to the northern most site median values of 1.93, 1.78, 1.53 and 1.54 ng m -3 TGM were detected. Compared with the median TGM concentration observed at the two Swedish sites, the regional background concentration near Berlin was elevated by about 25%. Whereas the 0.5 h average TGM concentration varies at the Swedish sampling sites in a very narrow range of only 0.69 ng m -3, a much broader range of 3.28 ng m -3 was observed at the southern sites. The increased TGM variability near Berlin was characterised by a diurnal cycle with a distinct maximum in the early morning hours (about 4:00 a.m.) before sun rise. The short time variability of the TGM concentration measured at the four sites on the south-to-north transect shows regional differences. A decreasing variability from the most southern to the most northern site became evident.