Abstract

The simultaneous transitions arising from the ν3 band of SF6 associated with the fundamental vibrations of N2 and O2 have been extensively studied. The integrated intensities, the bandwidths, and the frequency shifts of the maximal absorption have been examined as functions of the density of N2 or O2. A nonlinear effect on the integrated intensities resulting from changes in the density of SF6 was observed. The binary absorption coefficient deduced from experimental intensities has been compared with the absorption coefficient calculated by considering the theory developed by Ketelaar.

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