Simultaneous determination of benzothiazoles, benzotriazoles, and benzotriazole UV absorbers by solid-phase extraction-gas chromatography-mass spectrometry.

Abstract

Benzotriazoles (BTRs), benzothiazoles (BTHs), and benzotriazole ultraviolet absorbers (BUVs) are common products in plastic rubber and personal care products. Due to their toxicity and bioaccumulation, they have been identified as emerging contaminants (ECs) in the environment. Solid-phase microextraction (SPME) and solid-phase extraction (SPE) combined with gas chromatography-mass spectrometry (GC-MS) were used for the enrichment and detection of the contaminants in seawater and sediment, respectively. The conditions of SPE and SPME were optimized in terms of material, temperature, time, pH, ionic strength, extraction solvent, and elution solvent. Although SPME requires a small sample volume, it is not reliable for the extraction efficiency and reproducibility of BTHs, BTRs, and BUVs in seawater. However, the precision of SPE-GC-MS for the determination of BTHs, BTRs, and BUVs was around 10%, with recoveries of 67.40-102.3% and 77.35-101.8% in seawater and sediment, respectively. The limits of detection of 14 contaminants in seawater and sediment were 0.03-0.47ng/L and 0.01-0.58ng/g, respectively. Secondly, BTHs, BTRs, and BUVs were detected with low ecological risk when SPE-GC-MS was applied to the analysis of seawater and sediment samples from the Yangtze estuary and its adjacent areas. The SPE-GC-MS was highly precise with lower detection limits relative to previous studies and thus was able to meet the requirements for the detection of BTHs, BTRs, and BUVs in seawater and sediments.