Abstract

Abstract The new bidentate Ti catalyst, (anthraquinone-1,8-dioxy)bis(triisopropoxy-titanium) ( 1 ) can be successfully designed and utilized for the simultaneous coordination to carbonyl substrates. The high double-activation ability of the bidentate Ti catalyst 1 toward carbonyls is emphasized using several synthetic examples in comparison with the corresponding monodentate Ti catalyst. The intermediary coordination complex formation of bidentate 1 with DMF or epoxycyclohexane as a carbonyl or epoxy substrate is characterized by 13 C NMR spectroscopy.

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