Simultaneous application of cloud point and solid-phase extraction for determination of Fe(III) and Cu(II) ions by using SnO2nanopowder in micellar medium

Abstract

AbstractA new approach was developed for sensitive determination of Fe(III) and Cu(II) ions using SnO2 nanopowder in the micellar medium on the contrary conventional cloud point extraction studies. The presented method contains a combination of solid-phase extraction and cloud point extraction. According to this procedure, the metal ions were firstly retained on modified SnO2 nanopowder and then passed to the surfactant-rich phase. The effect of experimental variables including pH, concentration of reagents, eluting solution, incubation time, equilibration temperature, sample volume, and effects of interfering ions have been investigated and optimized systematically. The calibration graphs were linear in the range of 0.23–100.00 μg L−1 and 0.30–110.00 μg L−1 for Fe(III) and Cu(II), respectively. Under optimized conditions, the limits of detections were 0.07 and 0.09 μg L−1 for Fe(III) and 0.09 μg L−1 for Cu(II). The proposed method offers satisfactory analytical features by means of combining two differen...