Simulation study on heavy metals, phthalate esters, and organic halogens: Content and distribution characteristics during waste paper recycling.

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Imported waste paper and recycled pulp may contain pollutants, posing potential environmental risks to the ecosystem of China. This study examined the presence and distribution patterns of heavy metals, phthalate esters (PAEs), and adsorbable organic halogens (AOX) in recycled pulp and production wastewater after various recycling processes of three typical restricted types of imported waste paper. The results indicated that the concentration ranges of heavy metals, PAEs, and AOX in the three types of imported recycled waste paper were 21.61-40.38mg/kg, 15.35-27.88mg/kg, and 19.21-57.72mg/kg, respectively. The comparative analysis with the initial waste paper demonstrated a reduction in heavy metal content in the recycled pulp by 17.80-49.75%, PAEs by 65.42-90.55%, and AOX by 32.80-42.34%. The average concentrations of these pollutants in wastewater were 0.85-1.66mg/L, 27.28-59.86mg/L, and 1.15-3.34mg/L, respectively. Chromium and lead were identified as the primary heavy metals present in the waste paper. Following pulping, No. 1 and No. 2 met the arsenic and lead levels specified in the "Reuse Fiber Pulp" standard (GB/T24320-2021), whereas No. 3 met these criteria after de-inking only. The main PAEs detected in the waste paper were dibutyl phthalate and di(2-ethylhexyl) phthalate, most of which were removed during the pulping stage. Significantly higher levels of AOX were observed in No. 2 and No. 3 than in No. 1, with a minimal impact on AOX removal from the pulp during the recycling process.