Abstract

The shear and temperature fields in the filling process during gas penetration of gas-assisted injection molding (GAIM) of two kinds of high-density polyethylene (HDPE) with different molecular weights (Mw) were simulated numerically via Moldflow 6.1. The simulated results indicated that HDPE with higher Mw showed a relatively low shear rate in both the outer and inner zone of GAIM parts as compared to that with lower Mw, while the shear rate of the inner zone of the parts of the two materials were lower than that of the outer zone, which has a lower temperature and shorter time for crystallization. Considering the remarkable difference between their viscosities, a model of the shear thinning and recovering effects on crystallization during the GAIM process is proposed. Through the simulation, along with the analysis of their viscosities and rheological properties, the influence of molecular weight and shear and temperature fields on two special kinds of crystalline morphology (i.e., shish-kebabs and banded spherulites) during GAIM were interpreted.

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