Abstract
AbstractComputer simulation is well suited for theoretical investigation of coupled modification reactions of polymers to make subsequent comparison with experimental results. The percentage of units resulting in 1,4‐polybutadiene for substitution coupled with partial double bond shift is calculated for a simplified model. In the computer program three pseudo‐random number generators are used for simulation. The substitution degree SU and the shift degree SH describe the modification. In the general case, 22 chemically different units result. Borderline cases are SH = 0 with at most 3 units and SH/SU = 1,0 with at most 12 units. A detailed investigation is carried out for the especially interesting range SU = 0,1 to 0,5 and SH/SU = 0,1 to 0,5.
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