Abstract

Since preindustrial times, atmospheric CO2 content increased continuously, leading to global warming through the greenhouse effect. Oceanic carbon sequestration mitigates global warming; on the other hand, oceanic CO2 uptake would reduce seawater pH, which is termed ocean acidification. We perform Earth system model simulations to assess oceanic CO2 uptake, surface temperature, and acidification for Zhejiang offshore, one of the most vulnerable areas to marine disasters. In the last 40 years, atmospheric CO2 concentration increased by 71 ppm, and sea surface temperature (SST) in Zhejiang offshore increased at a rate of 0.16°C/10a. Cumulative oceanic CO2 uptake in Zhejiang offshore is 0.3 Pg C, resulting in an increase of 20% in sea surface hydrogen ion concentration, and the acidification rate becomes faster in the last decade. During 2020–2040, under four RCP scenarios, SST in Zhejiang offshore increases by 0.3–0.5°C, whereas cumulative ocean carbon sequestration is 0.150–0.165 Pg C. Relative to RCP2.6, the decrease of surface pH in Zhejiang offshore is doubled under RCP8.5. Furthermore, simulated results show that the relationship between CO2 scenario and oceanic carbon cycle is nonlinear, which hints that deeper reduction of anthropogenic CO2 emission may be needed if we aim to mitigate ocean acidification in Zhejiang offshore under a higher CO2 concentration scenario. Our study quantifies the variation characteristics of oceanic climate and carbon cycle fields in Zhejiang offshore, and provides new insight into the responses of oceanic carbon cycle and the climate system to oceanic carbon sequestration.

Highlights

  • Atmospheric CO2 concentration has reached 410.07 ± 0.10 ppm by 2019, and increased by 46% since preindustrial time, which is primarily resulting from human activities of fossil fuel burning and land use changes [1]

  • About 41% of these emissions stayed in the atmosphere, whereas about 24% of these emissions were absorbed by the ocean, which is considered as a main sink of atmospheric CO2 [1]

  • Model-simulated historical oceanic CO2 uptake for the global ocean is consistent with observation-based estimates reported by IPCC AR5 (Intergovernmental Panel on Climate Change Fifth Assessment Report) [46]

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Summary

Introduction

Atmospheric CO2 concentration has reached 410.07 ± 0.10 ppm (parts per million) by 2019, and increased by 46% since preindustrial time, which is primarily resulting from human activities of fossil fuel burning and land use changes [1]. About 41% of these emissions stayed in the atmosphere, whereas about 24% of these emissions were absorbed by the ocean, which is considered as a main sink of atmospheric CO2 [1]. The ocean plays an important role in regulating climate by key air–sea interaction processes [2,3,4,5,6]. Increased atmospheric CO2 causes global warming (GW) through the greenhouse effect. Global warming has become one of the most challenging global issues and the core issue of global change

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